Product ID:CHEMI-COTE UR-5000 PT B POLYURETHANE COATING
MSDS Date:12/06/1991
FSC:8010
NIIN:00N054832
Kit Part:Y
MSDS Number: BVZTS

GARLAND FLOOR CO

4500 WILLOW PKWY
CLEVELAND, OH 44125
US

Emergency Phone: 216-883-4100

Info Phone: 216-883-4100

Preparer: JWC

Cage: 0RA65

GARLAND FLOOR CO

CLEVELAND, OH 44125 US

Telephone: 216-883-4100

Cage: 0RA65

HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (HOMOPOLYMER

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

EXPOS TO ISOCYANATE AT LEVELS WELL BELOW

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CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF

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SEVERAL HOURS AFTER EXPOS. ONCE SENSITIZED AN

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COLD AIR/OTHER IRRITANTS. THIS INCREASED LUNG

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YEARS. SENSITIZATION MAY BE EITHER TEMPORARY OR

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MILK OR WATER TO DILUTE. DO NOT GIVE FLUIDS

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SYMPTOMATICALLY. DO NOT INDUCE VOMITING.

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CONC OF ISOCYANATES MAY BE KEPT TO A MIN BY NOT

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THRESHOLDS THAT ARE HIGHER THAN THE TLV/PEL.

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EXCEEDED ITS SERVICE LIFE, BREAK THROUGH OF THE

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BEING ABLE TO SMELL ISOCYANATE, HOWEVER, WHEN A

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WEARER OF VAP PARTICULATE RESP WILL BE WARNED OF

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1) ORG SOLVS HAVE LOW ODOR

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BREAK THROUGH FILTERS BEFORE ISOCYANATES DO. NOTE

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OF THIS PROD, CNDTNS OF ATM O*2-DEFICIENCY(<19.5%

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1910.134, AN ATM-SUPPLYING RESP MUST BE USED UNDER

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SHOULD BE WORN IF SKIN CONTACT IS LIKELY.

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AS MIN PROTECTION UNDER CONDITIONS WHERE SPLASH

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& TRANSPORTING OPEN CONTAINERS OF THIS MATERIAL.

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NOT BE CONSUMED IN AREAS IMMED TO USE OF THIS

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(PRIMARY HLTH RISK IS FROM PRLNGD
OVEREXP TO MONOMERIC ISOCYANATES. THE ISOCYANATE (HDI) PORTION OF
THIS PRODUCT HAS A VERY LOW VAP PRESS). ACUTE: CONTAINS MATLS THAT
MAY CAUSE CHEM BURN TO SKIN/EYES. HIGH CONC OF VAPS MAY CAUSE
SEVERE IRRIT OF EYES & RESP TRACT. TOXIC IF INGESTED. INHAL:
HEATING CAN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: GENERATE VAPORS THAT MAY CAUSE
HEADACHES, NAUSEA & RESP IRRIT. MAY CAUSE EYE IRRIT. MAY CAUSE MILD
SKIN IRRIT. PROD IS SLIGHTLY TOXIC UPON INGEST. CHRONIC: MAY CAUSE
SKIN SENSITIZATION, DERM ATITIS. PROD THAT IS REPRESENTATIVE OF
CURRENT MFG PROCESSES IS NOT BELIEVED TO BE CANCER HAZARD TO
HUMANS.(SUPP DATA)
Medical Cond Aggravated by Exposure:ASTHMA & OTHER RESPIRATORY
DISORDERS (BRONCHITIS, EMPHYSEMA, HYPERREACTIVITY), SKIN ALLERGIES,
ECZEMA.

First Aid:INHAL: REMOVE TO FRESH AIR. IF BRTHG HAS STOPPED, ADMIN ARTF
RESP & SEEK MD ATTN. ASTHMATIC-TYPE SYMPS MAY DEVELOP & MAY BE
IMMED/DELAYED UP TO SEVERAL HOURS. SKIN: REMOVE CONTAMD CLTHG &
THORO WASH C ONT AREA W/SOAP & WATER. GET MD ATTN IFIRRIT PERSISTS.
WASH CONTAMD CLTHG BEFORE REUSE. EYES: FLUSH EYES WITH PLENTY OF
WATER FOR AT LEAST 15 MINS. GET MD ATTN. INGEST: GIVE LGE QTYS OF
(ING 8)

Flash Point Method:PMCC
Flash Point:338F,170C
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
DURING FIRE, HDI VAPS & OTHER IRRIT, HIGHLY TOX GASES MAY BE
GENERATED BY THERM DECOMP. REMOVE (SUPP DATA)
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. WEAR APPROP
NIOSH/MSHA APPRVD PERS PROT EQUIP. DIKE SPILLS. ABSORB W/INERT
ABSORB MATLS & COLLECT IN OPEN CNTNRS FOR DISP. FLUSH CONTAMD AREA
W/WATER, COLLECTING FOR DISP. NOTIFY APPROP AUTHS IF NECESSARY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL DRY PLACE W/ADEQ VENT,
AWAY FROM OPEN FLAMES & HIGH TEMPS. KEEP CLOSURE TIGHT & CNTNR
UPRIGHT TO PVNT LEAKAGE. RESPIRABLE (ING 10)
Other Precautions:DO NOT HANDLE UNTIL THE MFRS SAFETY PRECAUTIONS HAVE
BEEN READ & UNDERSTOOD. WASH THORO AFTER HNDLG. DO NOT
FLAME-CUT/WELD AN EMPTY CNTNR/DRUM. OBSERVE CNDTNS OF GOOD
INDUSTRIAL HYGIENE & SAFE WORKING PRACTICE.

Respiratory Protection:USE A PROPERLY-FITTED NIOSH/MSHA APPRVD
CHEM/MECH RESP DESIGNED TO REMOVE A COMBINATION OF PARTICULATES &
ORGANIC VAPOR IF TLVS ARE EXCEEDED/ARE ANTIC TO BE EXCEEDED. NOTE
ON ODOR WARNING PROPERTIES: PURE ISOCYANATE MATLS HAVE ODOR(ING
11)
Ventilation:USE OF MECH DILUTION VENT (GENL &/LOC EXHST), ESPECIALLY IN
CONFINED AREAS, IS RECOMM TO MAINTAIN EXPOS BELOW TLV(S).
Protective Gloves:WORK GLOVES & PROT BARRIER CREAM(ING 19)
Eye Protection:USE SAFETY GLASSES W/SIDESHIELDS(ING 20)
Other Protective Equipment:USE PROTECTIVE CREAMS WHERE SKIN CONTACT IS
LIKELY. COVER AS MUCH OF THE EXPOSED SKIN AREA AS POSS W/APPROP
CLTHG.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING/USING WASH
ROOM. DO NOT SMOKE IN CHEM HNDLG/STOR AREA. FOOD/BEVERAGE
SHOULD(ING 22)
Supplemental Safety and Health
KEY1;T6.FIRE FIGHT PROC: ALL IGNIT SOURCES. CLSD CNTNR MAY EXPLO WHEN
EXPOS TO EXTREME HEAT/BURST WHEN CONTAMD W/ WATER(CARBON DIOXIDE
EVOLVED). EFTS OF OVEREXP: AS RSLT OF PREVIOUS RPTD OVEREXP/A SIN
GLE LGE DOSE, CERTAIN INDIVIDUALS MAY DEVELOP ISOCYANATE SENSIT
(CHEM ASTHMA). THIS MAY CAUSE THEM TO REACT TO A LATER (

HCC:T6
Boiling Pt:B.P. Text:999F,537C
Vapor Density:HVR/AIR
Spec Gravity:1.12
Evaporation Rate & Reference:SLOWER THAN BUAC
Solubility in Water:(REACTS SLOWLY)
Appearance and Odor:CLEAR/PALE YELLOW WITH NEGLIGIBLE ODOR.
Percent Volatiles by Volume:0.0

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, ALCOHOLS, STRONG BASES, METAL COMPOUNDS, SURFACE ACTIVE
MATERIALS.
Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAMES, SPARKS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN, HCN, HDI.
Conditions to Avoid Polymerization:COULD OCCUR UNDER NORMAL CONDITIONS,
CARE MUST BE TAKEN.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE
HANDLED WITH CARE DUE TO PRODUCT RESIDUE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.